Dislocation-enhanced electrical conductivity in rutile TiO2 accessed by room-temperature nanoindentation

H. Bishara; H. Tsybenko; S. Nandy; Q. K. Muhammad; T. Frömling; X. Fang; J. P. Best; G. Dehm

Scripta Materialia 212 (2022) 114543-114543

Dislocation-enhanced electrical conductivity is an emerging topic for ceramic oxides. In contrast to the majority of present studies which focus on large-scale crystal deformation or thin film fabrication to introduce dislocations, we use a nanoindentation “pop-in stop” method to locally generate 〈011〉 edge-type dislocations at room temperature, without crack formation, on the (100) surface of a rutile TiO2 single-crystal. Ion beam assisted deposition of microcontacts allowed for both deformed and non-deformed zones to be locally probed by impedance spectroscopy. Compared to the dislocation-free region, a local enhancement of the electrical conductivity by 50% in the dislocation-rich regions is found. The study paves the way for local “mechanical-doping” of ceramics and oxide materials, allowing for the use of dislocations to tune the local conductivity with high spatial resolution.

DOI: https://doi.org/10.1016/j.scriptamat.2022.114543